Viscosity and self-diffusivity of ionic liquids with compressed hydrofluorocarbons: 1-Hexyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)amide and 1,1,1,2-tetrafluoroethane

Abstract

The viscosity and self-diffusivity of mixtures of the ionic liquid, 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ([HMIm][Tf2N]), and the compressed gas, 1,1,1,2-tetrafluoroethane (R-134a), were measured at three different temperatures (298.15 K, 323.15 K, 343.15 K) and pressures to 21 bar. The high-pressure vapor-liquid equilibrium (VLE) of the ionic liquids with R-134a was measured to calculate the composition of the liquid phase at the various pressures encountered in the viscosity and diffusivity measurements. The viscosity of the ionic liquid decreases significantly with increased composition of R-134a at VLE. The “excess” viscosity demonstrates positive values that are believed to represent relatively strong intermolecular forces of the polar R-134a and [HMIm][Tf2N]. The self-diffusivity of mixtures of [HMIm][Tf2N] and liquefied R-134a (298.15 K and 6.7 bar) was measured and increases significantly with increases in the composition of R-134a. The self-diffusivity of [HMIm][Tf2N] in vapor-liquid equilibrium with compressed R-134a gas was measured and indicates similar increases in diffusivity with composition of R-134a. The diffusivity demonstrates close Stokes-Einstein behavior using the measured mixture viscosity data and ambient pressure self-diffusivity.