Viscosity and rheological behaviour of carbon dioxide-expanded fish oil triglycerides: Measurement and modeling

Abstract

Viscosity and rheological behaviour of carbon dioxide-expanded (CX) fish oil (FO) triglycerides (CXFO) were determined at 40, 55, and 70 °C at pressures of up to 12 MPa using a rotational rheometer equipped with a high pressure cell at shear rates of 100–500 s −1. The mass fraction of CO 2 ( w CO 2 ) in CXFO was determined at 40 and 55 °C at pressures of up to 25 MPa. The viscosity of CXFO determined at a shear rate of 300 s −1 decreased substantially with pressure due to dissolution of CO 2 in FO. Decrease in viscosity with pressure and hence w CO 2 was temperature dependent. The viscosity of CXFO decreased with a pressure increase from 0.1 to 12.2 MPa by about 90% (25 to 2.65 mPa s) and 70% (11.6 to 3.38 mPa s) at 40 °C and 70 °C, respectively. A new empirical model correlating the viscosity of CXFO to temperature and pressure was developed. The viscosity decreased up to w CO 2 levels of about 30% (w/w) then approaching a constant level. CXFO viscosity data were successfully correlated to w CO 2 and pure component viscosities using the empirical Grunberg and Nissan model. Rheological measurements showed dilatant flow behaviour for CXFO at elevated pressures, with the flow behaviour index approaching 1.5 at 12.4 MPa. Novel process development and design of equipment will benefit from a better understanding of such rheological behaviour.