Abstract
Vinylidene ruthenium complexes were prepared from trichloronitrosylbis(phosphine)rutheniums and terminal alkynes, subsequent cycloaddition of methyl propiolate to the vinylidene complexes giving rise to unusual ruthenacyclobutene species; in these transformations, an interesting electrostructurally-flexible behaviour of the NO ligand was observed.
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Schedule a callMore From: Journal of the Chemical Society Chemical Communications
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