Abstract
We applied the resonant two-photon ionization and mass-analyzed threshold ionization spectroscopic techniques to record the vibronic and cation spectra of m-chloroaniline. The band origin of the first electronic transition was found to be 33 658 ± 2 cm −1, whereas the adiabatic ionization energy was determined to be 63 958 ± 5 cm −1. Within our experimental detection limit, these measured values are the same for both of the 35Cl and 37Cl isotopomers. The observed active modes of this molecule in the electronically excited S 1 and cationic ground D 0 states mainly involve the in-plane ring deformation and substituent-sensitive bending vibrations.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
