Abstract
Besides two strong π∗⊥1 and π∗∥ resonances in the 398- to 400-eV energy range, N 1s near edge x-ray absorption fine structure spectra of acrylonitrile molecules have a less intense 401- to 403-eV doublet. The two components correspond to the N 1s → π∗⊥2 and N 1s → D∗∥ transitions, where D∗∥ is a diffuse state with strong Rydberg character. The vibrational analysis shows that in the D∗∥ excited state, two low-energy out-of-plane normal modes are strongly excited. The π∗⊥2 excitation triggers a set of in-plane vibrations, in particular, two C=C–C≡N bendings of the molecule.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
