Abstract
SynopsisWe present a study of the vibrationally resolved B 1s photoionization cross section of the BF3 molecule. A combination of high-resolution photoelectron spectroscopy measurements and of state-of-the-art calculations shows the evolution of the photon energy dependence of the cross section from a complete trapping of the photoelectron wave (low energies) to oscillations due to intramolecular scattering. These diffraction patterns allow to access structural information of both the neutral molecule and the core -hole species generated upon photoabsoption.
Highlights
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Synopsis We present a study of the vibrationally resolved B 1s photoionization cross section of the BF3 mo lecule
A co mb ination of h igh-resolution photoelectron spectroscopy measurements and of state-of-the-art calcu lations shows the evolution of the photon energy dependence of the cross section from a co mplete trapping of the photoelectron wave to oscillat ions due to intramolecular scattering [1, 2]. These diffract ion pa tterns allow to access structural information of both the neutral mo lecule and the core -hole species generated upon photoabsoption [3]
Summary
HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. Home Search Collections Journals About Contact us My IOPscience Resolved B 1s photoionization cross section of BF3
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