Abstract
Abstract Frequency fluctuation of the NO stretching mode of the sodium nitroprusside, [Fe(CN)5NO]2−, in H2O and D2O was studied by three-pulse infrared photon echo spectroscopy. It is found that the time-correlation function of the frequency fluctuation of this mode is characterized by time constants similar to those of the triply degenerate T1u mode of the CN stretching of [Fe(CN)6]4−, showing that the vibrational frequency fluctuation is not dominated by the time-dependent anisotropic solute–solvent interaction.
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