Abstract
For the first time the investigation of water molecule complexed with CS2 molecule in solid neon was performed in a large frequencies range from near to far infrared using Fourier transform infrared spectroscopy. From concentration effects and with the help of theoretical results we have identified several vibrational transitions for CS2 dimer, CS2H2O, CS2-(H2O)2 and (CS2)22O complexes. We have also highlighted the presence of two isomers for CS2H2O. Theoretical calculations at the second-order Møller-Plesset level (MP2) have been performed to obtain the equilibrium geometries and vibrational spectra at the harmonic level and comparison with experimental data allows us to give structures of observed complexes. Finally, the results are compared with thoses of the isolectronic complexes N2OH2O, CO2H2O, and OCS-H2O previously published.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callSimilar Papers
More From: Journal of Molecular Structure
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
