Abstract
We demonstrate strong coupling between surface plasmon resonances and molecular vibrational resonances of poly(methyl methacrylate) (PMMA) molecules in the mid-infrared range through the use of grating coupling, complimenting earlier work using microcavities and localized plasmon resonances. We choose the period of the grating so that we may observe strong coupling between the surface plasmon mode associated with a patterned gold film and the C=O vibrational resonance in an overlying polymer film. We present results from experiments and numerical simulations to show that surface plasmon modes provide convenient open cavities for vibrational strong coupling experiments. In addition to providing momentum matching between surface plasmon modes and incident light, gratings may also produce a modification of the surface plasmon properties, notably their dispersion. We further show that for the parameters used in our experiment surface plasmon stop bands are formed, and we find that both stop-band edges undergo strong coupling.
Highlights
We demonstrate strong coupling between surface plasmon resonances and molecular vibrational resonances of poly(methyl methacrylate) (PMMA) molecules in the mid-infrared range through the use of grating coupling, complimenting earlier work using microcavities and localized plasmon resonances
In addition to allowing momentum matching, the grating nature of the metallic surface modifies the dispersion of the surface plasmon modes, introducing surface plasmon stop bands.[13−16] This extra degree of freedom allows us to make a first exploration of the interaction of surface plasmon stop bands and hybrid vibropolariton states produced via strong coupling
It is useful to first look at the modes supported by the structures we investigate, and this we did through a numerical simulation performed using the commercial finite-element software COMSOL
Summary
We demonstrate strong coupling between surface plasmon resonances and molecular vibrational resonances of poly(methyl methacrylate) (PMMA) molecules in the mid-infrared range through the use of grating coupling, complimenting earlier work using microcavities and localized plasmon resonances. We investigate the strong coupling of vibrational molecular resonances with the infrared surface plasmon modes associated with metal surfaces.
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