Abstract

We present the computation of two-photon transition spectra between rovibrational states of the $\text{H}_{2}{}^{+}$ molecular ion, including the effects of hyperfine structure and excitation polarization. The reduced two-photon matrix elements are obtained by means of a variational method. We discuss the implications of our results for high-resolution spectroscopy of $\text{H}_{2}{}^{+}$.

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