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Abstract
A full interpretation was carried out for the vibrational spectra of TiR3, where R= -CH2C6H5, -CH2C(CH3)2C6H5, and-CH2Si(CH3)3. The absorption bands for the Ti-C bonds were delineated. A dimeric structure was established for the compounds studied with a Ti-Ti bond, whose band lies at 230–280 cm−1. There is an interaction of the titanium atom with the β-carbon atom of the ligand for the Ti(III) benzyl and neophyl derivatives.
Published Version
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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