Abstract
The Raman spectra of Ca3SiO5 have been successfully obtained at temperatures up to 1353 K by a continuous‐wave ultraviolet Raman spectroscopic system. The Raman spectra do not change significantly with an increase in temperature, despite triclinic (T)→monoclinic (M)→rhombohedral (R) transitions. The present result is described in terms of the parameter related to temperature variation at constant pressure, defined in a manner similar to the Gruneisen parameter. Raman bands located above 350 cm−1 show smaller values of the parameter than lower frequency modes, suggesting that these higher frequency modes are assigned to SiO4 internal modes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
