Abstract
The ionization energy of 2-cyanophenol has been measured by both photoionization efficient spectroscopy and mass analyzed threshold ionization technique. The precise ionization energy of 2-cyanophenol is determined to be 73118 ± 5 cm−1 for the first time. The vibrational spectra of the cation are measured and analyzed in detail based on DFT calculations. The most active normal modes in the D0 state are assigned to the in-plane ring deformation.
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