Abstract
The i.r. (4000-30 cm −1) and Raman (4000-O cm −1) spectra of dimethyltelluride, dimethyltellurium difluoride and their deuterated analogs have been obtained. All the active fundamentals of these compounds except methyl torsions were assigned, assuming a C 2υ molecular symmetry for both the tellurides. Normal coordinate calculations have been made in order to confirm the proposed assignments. The skeletal bond strength of the tellurides together with that of TeF 4 are discussed, using the valence stretching force constants.
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