Abstract

The IR and Raman spectra ofSn(CF 3) 4 have been recorded and analyzed by means of a normal coordinate analysis. The molecular structure has been determined by electron diffraction yielding the geometric parameters ( T d symmetry) τ a(CF) 133.8(2) pm, τ a(SnC) 220.1(5) pm and ∠FCF 108.2(2)°. Compared with Sn(CH 3) 4, the SnC bonds are weakened and lengthened by 5.8(6) pm.

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