Abstract

The i.r. and Raman spectra of MeBr 2CCBr 2Me, in the crystalline state, are reported. The i.r. spectra of the same substance in dilute solutions in nonpolar solvents have also been obtained. Taking the CBr stretching bands as a guide to qualitative understanding of the experimental results it is shown that point group C 2 h is a reasonable working approximation to the molecular symmetry. On this basis it has been possible to obtain nearly complete vibrational assignment for the molecule.

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