Abstract
Infrared spectra (from 4000 to 400 cm −1) of solid, liquid and gaseous 1,1-diethylcyclopropane and Raman spectra of the condensed phases of this compound have been recorded. Evidence for two conformational isomers, one of which vanishes in the polycrystalline solid phase, is found in the spectral data for the liquid phase. It has been concluded that these two rotational isomers are the gauche/gauche conformers which arise when the two methyl groups are displaced in a conrotatory sense ( C 2 symmetry) and a disrotatory sense ( C s symmetry) from a hypothetical cis/cis ( C 2υ) structure. These conclusions are consistent with the conformational results previously obtained for ethylcyclopropane and ethyloxirane. In addition, from the variable temperature liquid phase Raman intensity measurements, the C 2 rotamer of 1,1- diethylcyclopropane has been calculated to be 1.1 ± 0.2 kcal/mole more stable than the C s form, and is the sole conformer remaining in the solid phase. Tentative vibrational assignments, in agreement with those for related molecules, are proposed for the major spectral bands of 1,1-diethylcyclopropane.
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More From: Spectrochimica Acta Part A: Molecular Spectroscopy
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