Abstract

The infrared spectrum at a resolution of 0.06 cm −1 has been recorded for vinylsilane. Vibrational-rotational analysis has been carried out on ν 6, ν 13, ν 15, and the strongly coupled pair of ν 12 and ν 19. The rotational constants and some of the distortion constants have been determined for ν 6, ν 13, and ν 15, whereas higher resolution of 0.004 cm −1 was required to obtain similar data from the coupled pair of ν 12 and ν 19. These data are compared to the ground state constants previously obtained from the microwave spectrum.

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