Year-end Sale % OFF 
Abstract
The nonlinear Bastiansen-Morino shrinkage effects are studied for (a) planar symmetrical XY 3, and (b) tetrahedral XY 4 molecular models. In both of these cases the so-called anharmonicity terms vanish. The shrinkage effects are expressed algebraically in terms of the mean-square amplitude matrix elements. Numerical values are given for the trihalides of boron, and germanium tetrachloride. In the case of GeCl 4 the result is compared with that from electron-diffraction data. Finally, the electron-diffraction r g values for this molecule are refined to fit accurately the presently calculated shrinkage effect.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
