Abstract

Vibrational energy transfer in S 1 p-difluorobenzene has been studied at lowtemperature within a supersonic free jet. Quantitative relative cross sections for the state-to-state vibrational energy transfer'channels (i.e. flow patterns) from the 8'vibrational level (e vib =346 cm -1 ) were obtained forlow energy collisions (T≃20-35 K) with He and Ar. They are qualitatively similar to analogous flow patterns obtained earlier from the 0 o level for room temperature (300 K) collisions with He and Ar

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