Abstract
Vibrational relaxation in D 2-Kr and D 2-Kr-He mixtures has been measured behind incident shock waves in the temperature range 1400–3500°K, and values of ▪, the vibrational relaxation time of D 2 infinitely dilute in one atmosphere pressure of He, are derived. These values are compared with calculations closely approximating exact one-dimensional quantum mechanical results, which were obtained using H 2-He potential parameters from recent theoretical and experimental determinations.
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