Abstract
The vibrational energy relaxation (VER) of the hydrogen stretch in a linear hydrogen-bonded complex dissolved in a polar solvent is studied. The study is based on the Azzouz-Borgis model [Azzouz, H.; Borgis, D. J. Chem. Phys. 1993, 98, 7361], which is known to account for many important features of real hydrogen-bonded systems, including ionic-to-covalent tautomerism and a broad distribution of hydrogen stretch frequencies. A description of VER in this strongly coupled system is considered, which consists of the following three consecutive steps: (1) solvation on the adiabatic excited vibrational surface; (2) nonadiabatic transition from the excited to the ground adiabatic vibrational surface; and (3) solvation on the adiabatic ground vibrational surface. The relaxation dynamics during those three steps were simulated via the mixed quantum-classical Liouville method, where the hydrogen is treated quantum-mechanically, while the other particles are treated in a classical-like manner. The solvation on the excited-state surface was found to occur rapidly ( approximately 0.5 ps) and to involve energy exchange with both the intramolecular and intermolecular degrees of freedom. It was also found that, while energy is released to the solvent during the solvation of the covalent tautomer, the solvation of the ionic tautomer involves absorption of energy from the solvent. The decrease in the transition frequency during the solvation process also facilitates the nonadiabatic transitions, which occur rapidly ( approximately 0.8 ps) thereafter. The nonadiabatic transitions were shown to be induced by interactions with a large number of solvent molecules and to be relatively insensitive to their location relative to the complex. Finally, solvation on the ground-state surface was seen to occur on a time scale of approximately 1.0 ps and leads to nonequilibrium ionic and covalent subpopulations. Equilibration on the ground-state surface occurs on a significantly slower time scale ( approximately 7.6 ps). Our results shed new light on the problem of VER in strongly coupled condensed phase systems that lie outside the range of validity of the Landau-Teller formula.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.