Abstract

The influence of spectrometer slit-widths upon the shapes of some vibrational absorption bands has been examined. The apparent band widths, apparent extinction coefficients at band peaks, and integrated band areas were measured under different conditions. The relative significance of extinction coefficients and integrated intensities for quantitative work has been considered, and some general conclusions have been drawn about the difficulties of applying the convenient procedures previously worked out by ramsay for determining the true band intensities.

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