Abstract
Asymmetric Fano‐line profiles have been observed by autoionization for specific vibrational excitation of Rydberg series in jet‐cooled naphthalene. The line shapes were analyzed in terms of degenerate resonance interference between optically active discrete and continua states. Observed linewidths were as narrow as 6 cm−1 for naphthalene and 3 cm−1 for naphthalene‐d8.
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