Abstract
One-photon MATI spectra of phenylacetylene and benzonitrile were obtained by using vacuum ultraviolet radiation generated by four-wave difference frequency mixing in Kr. Accurate ionization energies of phenylacetylene and benzonitrile were determined from the positions of the 0−0 bands, which are 8.8195 ± 0.0006 and 9.7288 ± 0.0006 eV, respectively. Vibrational frequencies of the molecular ions were determined from the spectra also. Assignments were made by utilizing the symmetry selection rule and frequencies and Franck−Condon factors calculated at the BP86, B3LYP, and B3PW91 density functional theory levels with the 6-311++G(2df,2pd) basis set.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
