Abstract
A weakly bound van der Waals complex is formed between cyclopropane and boron trifluoride dissolved in liquid argon or liquid nitrogen. A complexation enthalpy of −7.8(6) kJ mol−1 was determined by analysis of infrared spectra recorded at several temperatures between 93 and 125 K of a solution in liquid argon. Ab initio calculations at the MP2/6-31 + G(d) level gave insight into the structure of the complex, shown here, and supported the assignment of the vibrational spectra.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
