Abstract

A zero-order normal coordinate analysis was made for the in-plane vibrations of p-, m- and o-aminobenzonitrile and 2-chloro, 5-aminobenzonitrile by transferring the force constants from our earlier work. The observed and calculated frequencies agree with an average error of 19.3 cm −1. Unambiguous vibrational assignments of in-plane fundamentals of the four molecules have been made, and several assignments suggested by earlier workers have been revised.

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