Abstract
Normal coordinate analysis of methylphosphonic acid and its anions, is reported. Symmetry force constants were obtained using the method of Becher and Mattes. The fundamental vibrations are described by the potential energy distribution. An approximate method for the calculation of the errors on the symmetry force constants, due to the uncertainties on the vibrational frequencies, is presented. A discussion on the prediction of the CD 3 rocking mode is given.
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