Abstract

The pathways for energy transfer between CH 3Br and HCN have been determined along with their relative importance. The rate of vibrational energy transfer from CH 3Br(ν 6) to HCN(ν 2 has been determined to be 75 ± 25 ms −1 Torr −1. The factors which determine the relative importance of intermolecular vibrational energy transfer pathways will be discussed.

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