Abstract
The sequential contact transformation technique is applied to the vibration-torsion-rotation polarizability tensor operator for a molecule containing a threefold symmetric internal rotor. Detailed discussions about various types of polarizability tensor operators and corresponding vibration-torsion-rotation transitions are presented. The formalism of the transformed polarizability tensor operator makes it possible to analyze various high-order vibration-torsion-rotation interactions and their effects as well as to determine the intensities of transitions between vibration-torsion-rotation states within the Raman spectrum of the molecule. As an example, the transition matrix elements of the transformed polarizability tensor operators are discussed for CH3OH-like molecules.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
