Abstract
The contribution of an exponential and a gaussian short range force to vibration-to-vibration energy exchange is calculated in the impact parameter approximation. For near-resonant conditions, an inverse temperature dependence of the exchange probability is predicted. Estimates of selected exchange probabilities predicted by this theory are made for CoCo, HClHCl and HBrHBr. These results are in all cases greater than the predictions of SSH theory and are close to the experimental values for HCl-HCl and HBr-HBr.
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