Abstract

The contribution of an exponential and a gaussian short range force to vibration-to-vibration energy exchange is calculated in the impact parameter approximation. For near-resonant conditions, an inverse temperature dependence of the exchange probability is predicted. Estimates of selected exchange probabilities predicted by this theory are made for CoCo, HClHCl and HBrHBr. These results are in all cases greater than the predictions of SSH theory and are close to the experimental values for HCl-HCl and HBr-HBr.

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