Abstract
Photometric titration curves have been analysed in terms of the hyperbola form derived from a plot of a linearly related variable, in the absence of an indicator. Titration curves can be evaluated for the formation of ML-type complexes even when these are considerably dissociated, i.e., when the product of the formation constant and the concentration of the species being determined falls as low as unity. Limiting conditions for the successful evaluation of curves are discussed. The applicability of the method has been checked on practical systems.
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