Abstract
Abstract Oswal, S.L., Oswal, P. and Dave, J.P., 1994. V E of mixtures containing alkyl acetate, or ethyl alkanoate, or ethyl bromoalkanoate with n -hexane. Fluid Phase Equilibria , 98: 225-234. Excess volumes, V E , have been determined from density measurements using a vibrating tube densimeter (DMA 60/602) at 303.15 K for ten binary mixtures of ethyl acetate, ethyl propionate, ethyl butyrate, amyl acetate, decyl acetate, dodecyl acetate, ethyl-2-bromopropionate, ethyl-3-bromopropionate, ethyl-2-bromobutyrate and ethyl-4-bromobutyrate with n -hexane. The molecular size of alkanoate and the position of the bromine atom in bromoalkanoate has the predominant effect on V E . The experimental results have also been analysed using the Prigogine-Flory-Patterson theory employing both the van der Waals and the Lennard-Jones energy models.
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