Abstract

Reaction of ZnCl2 or ZnBr2 with 4-(3-pyridinyl)-1,2,4-triazole (pytrz) yields two novel 1D coordination polymers, [Zn(pytrz)Cl2]n (1) and [Zn(pytrz)Br2]n (2). Their crystal structures have been determined using X-ray single crystal diffraction analysis. Their subsequent reactions with additional NaClO4 resulted in a re-assembled molecular structure, [Zn3(pytrz)6(H2O)6](ClO4)3 (3), featuring a linear trinuclear complex. In this work, conversion from 1D to 0D triggered by anion-induce have been achieved based on pytrz. ClO4− anions may act as the templates during the re-assembly and all of the three complexes exhibit strong blue fluorescence emission bands in the H2O solution at ambient temperature.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.