Abstract
The vibrational energy levels for the X1Σ+ and B1Σ+ states of the HF molecule were calculated by the variational method from the corresponding Rydberg–Klein–Rees potentials. The eigenvectors were used to obtain the rotational constants, Bv, Dv and Hv, according to the perturbation theory definitions. The dipole moment function, its rotationless matrix elements and the radiative lifetimes for the vibrational levels corresponding to v= 1, 2, 3 of the ground state were also calculated.
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