Abstract
The variational technique which is proposed earlier [J. Chem. Phys. 53, 1931 (1970)] is applied for the prediction of the excess thermodynamic properties of binary liquid mixtures. The results are compared with the experimental and machine-calculated, Monte Carlo, data. Also comparisons are made with the results of the other theories of mixtures. It is shown that the variational technique is a stronger tool for quantitative predictions of the excess thermodynamic properties of liquid mixtures than the other existing theories of mixtures.
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