Abstract

The so-called effective exchange parameter J0 of the classical Heisenberg Hamiltonian for magnetic interactions is investigated as a function of volume and occupation of the valence band across 3d-transition-metal series in face-centered-cubic (fcc) metals, from Mn to Ni. We show that there exists a particular area in the volume-electron concentration phase space, where the effective exchange parameter behaves anomalously. The peculiarity, in combination with deviations of the electronic structure in real alloys from the rigid-band behavior, should lead to highly frustrated magnetic configurations that were predicted theoretically for the fcc Invar alloys.

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