Vapour side corrosion in a ME desalination plant at Jebel Dhana

Abstract

Jebel Dhana, from the Abu Dhabi Water and Electricity Authority (ADWEA), operates two 2 MGD multi-effect thermo-compression distillers commissioned in 1996. Tube failures were first reported approximately 16 months after commissioning. The initial tube failures were from the upper rows, but more recent failures were apparently randomly distributed throughout the tube bundle. Ten tubes were removed and their corrosion morphology was examined macroscopically and microscopically. The corrosion products were analysed by X-ray, EDAX, and EPMA techniques. The 90 10 copper nickel alloy tubes were found to have suffered from vapour side corrosion; however, there was no sign of any copper oxide deposition, as has often been seen in failed tubes from MSF distillers. The failures took two forms: corrosion fatigue cracking, and pitting corrosion. The corrosion fatigue was in the form of a circumferential crack at a flat portion of the tube in the centre of a tube span. It was believed that the flat surface had developed as a result of fretting against a neighbouring tube, and had been worn away to the point of failure. Unfortunately, the position of the tubes in the tube bundle had not been identified during their removal, but it is suspected that the damaged tube had been in the top row, with the flattened portion directly below one of the two vapour inlet pipes. The other tubes sampled showed pitting corrosion. Some of the pitting had perforated the tube walls whilst others showed pitting on the outer surface only. Some of the pits contained corrosion products whilst others were free of them. This pitting corrosion is attributed to the formation of carbonic acid in the presence of oxygen (air). A weak acid is formed due to the dissolution of CO 2 in the condensing water vapour. The gas concentration varies within the tube bundle, due to the vapour phase, allowing the gas concentration to increase in specific areas of the tube bundle, causing the non-uniformity of attack. There was no immediate tie-up between the pitting corrosion and the two steam inlet pipes due to the unknown position of the sampled tubes within the tube bundle. It is recommended that the oxygen level be reduced by ensuring that the distiller vessels are as air-tight as possible, thus reducing the tendency towards pitting corrosion.