Abstract

Binary vapor−liquid equilibrium data were measured for the n-butane (HC-600) + difluoromethane (HFC-32), + pentafluoroethane (HFC-125), 1,1,1,2-tetrafluoroethane (HFC-134a) systems at temperatures from 313.15 K to 333.15 K. These experiments were carried out with a circulating-type apparatus with on-line gas chromatography. The experimental data were correlated well with the Peng−Robinson equation of state using the Wong−Sandler mixing rules.

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