Abstract
AbstractMetallic sublimates coated by sulfides and chlorides line the vesicle walls of mafic volcanic lava and bombs from Kīlauea, Vesuvius, Etna, and Stromboli. The metallic sublimates were morphologically and compositionally similar among the volcanoes. The highest concentrations of S and Cl occurred on the surface of the sublimates, while internally they had less than 1 wt % S and Cl in most cases, leading us to classify them as alloys. The major components of the alloys were Cu, Sn, Co, and Ag based on electron microprobe analyses and environmental scanning electron microscope element maps. Alloy element maps showed a covariance of Cu-Sn, while Co and Ag concentrations varied independently. Laser ablation-inductively coupled plasma-mass spectrometry analysis of matrix glass and melt inclusions in bombs from Stromboli showed appreciable amounts of Cu, Co, and Sn. We propose a model for the origin of the metallic grains, which involves syneruptive and posteruptive magma degassing and subsequent cooling of the basalt vesicles. During syneruptive vapor phase exsolution, volatile metals (Cu, Co, and Sn) partition into the vapor along with their ligands, S and Cl. The apparent oxygen fugacity (fO2) in these vapor bubbles is low because of the relative enrichment of the exsolved gas phase in H2 relative to H2O in silicate melts, due to the much higher diffusivity of the former in silicate melts. The high fH2 and low fO2 induces the precipitation of metal alloys from the vapor phase. Subsequently, the reducing environment in the vesicle dissipates as the cooling vapor oxidizes and as H2 diffuses away. Then, metal-rich sulfides (and chlorides) condense onto the outer surfaces of the metal alloy grains either due to a decrease in temperature or an increase in fO2. These alloys provide important insights into the partitioning of metals into a magmatic volatile phase at low pressure and high temperature.
Highlights
From their studies of the 1991 eruptive products of Mount (Mt.) Pinatubo (Philippines) and the giant Bingham Canyon porphyry Cu deposit in Utah, Hattori and Keith (2001) concluded that mafic magma was fundamental in delivering sulfur and chalcophile elements to overlying magma chambers and could contribute to the formation of economic deposits
The magmatic volatile phase (MVP) and associated metals can rise through low-viscosity magma or may be transported via magma convection followed by escape to the atmosphere during open-system degassing
Our finding of Cu-Sn-Co-Ag metal alloys in volcanic rocks from Kīlauea, Etna, Vesuvius, and Stromboli suggests that metal partitioning to the vapor phase exsolving from mafic magmas at low pressure is a common process
Summary
From their studies of the 1991 eruptive products of Mount (Mt.) Pinatubo (Philippines) and the giant Bingham Canyon porphyry Cu deposit in Utah, Hattori and Keith (2001) concluded that mafic magma was fundamental in delivering sulfur and chalcophile elements to overlying magma chambers and could contribute to the formation of economic deposits. Commun., 2004) found preliminary evidence of vapor transport of Cu in bombs that had erupted from the Miyake-jima volcano only a few days earlier. To test these conclusions, fresh, recently erupted mafic magma needs to be examined from volcanoes worldwide. We sampled active flows from the Pu‘u ‘Ō‘ō vent on Kīlauea volcano, Hawaii. In a preliminary report, Strand et al We have examined bombs and flows from other active volcanoes, including Etna, Vesuvius, and Stromboli. As we report here, we found the same metallic alloys, with
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