Abstract

Measurements were made of the vapor pressures of zirconium tetrafluoride by using a torsion effusion apparatus. The temperature dependence fit the equation: log(p/Pa) = (15.20 ± 0.15) − (11 900 ± 200)/(T/K) (from 685 to 828 K). The compound vaporizes congruently in the monomeric form. With treatment of the measured vapor pressures by second- and third-law methods, the standard sublimation enthalpy ΔsubH°(298 K) = (239 ± 2) kJ·mol−1 was obtained.

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