Abstract

This study reports the bubble-point compositions in the low-temperature region of the methane-carbon dioxide phase diagram. Liquid compositions in equilibrium with vapor were measured as a function of pressure on isotherms at -65.00/sup 0/, -81.40/sup 0/, -94.00/sup 0/, -112,00/sup 0/, -130.00/sup 0/, -148.00/sup 0/, and -184.00/sup 0/F (-53.89/sup 0/, -63.00/sup 0/, -70.00/sup 0/, -80.00/sup 0/, -90.00/sup 0/, -100.00/sup 0/, and -120.00/sup 0/C). The smoothed results were combined with previous dew-point data to provide tables and plots of isobaric and isothermal K values. The experimental method used was the vapor-recycle method in a temperature-controlled equilibrium cell with chromatographic analysis of the phases. (12 refs.)

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