Abstract
Vapor-liquid equilibrium data for the binary systems α-pinene + (S)-(-)-limonene and β-pinene + (S)-(-)-limonene were determined at 53.3 and 80.0 kPa in a modified miniature Othmer still. Parameters of the Wilson, NRTL, and UNIQUAC equations were calculated with the aid of a Nelder-Mead technique to minimize an objective function based on the total pressure. The results were compared with the predictions of the UNIFAC method.
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