Abstract

The vapor-liquid phase behavior of the propane-acetone system under equilibrium conditions has been established experimentally at 325, 350, 375, 400 and 425 K. Under these conditions pressures up to 4666.4 kPa (676.8 psia) were obtained. The composition of the vapor and liquid phases in equilibrium, in conjunction with data available in the literature for the critical state behavior of this system, has permitted the establishment of the complete vapor-liquid equilibrium behavior of the propane-acetone system for temperatures ranging from 325 K up to the critical temperature of acetone ( T c = 508.1 K). The K-constants resulting from this experimental study when related to pressure produced isothermal relationships that follow a normal behavior and which do not exhibit any azeotropic tendencies.

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