Abstract
Binary vapor–liquid equilibrium data were measured for the carbon dioxide (CO 2) + 2,2-dichloro-1,1,1-trifluoroethane (R123) system and the carbon dioxide (CO 2) + 1-chloro-1,2,2,2-tetrafluoroethane (R124) system at temperature from 313.15 to 333.15 K. These experiments were carried out with a circulating-type apparatus with on-line gas chromatography. The experimental data were correlated well by Peng–Robinson equation of state using the Wong–Sandler mixing rules.
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