Abstract
The reaction of (Me(3)Si)(2)TIP with V(NNMe(2))(OAr)(3) results in the production of V(NNMe(2))(TIP)(OAr), where TIP is 2-((2-thiolatophenylimino)methylene)phenolate. The aryloxide is readily displaced by ISiMe(3) to form an insoluble iodide complex formulated as V(NNMe(2))(TIP)(I). The iodide was used to prepare three different complexes: [V(NNMe(2))(TIP)(dmpe)]I, [V(NNMe(2))(TIP)(Bu(t)bpy)][OTf], and [V(NNMe(2))(TIP)(Bu(t)bpy)][SbF(6)]. The phosphine derivative, [V(NNMe(2))(TIP)(dmpe)]I, was characterized by X-ray diffraction and shows a quite short N-N distance of 1.293(3) A indicative of a dominant isodiazene resonance form.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
