Abstract

Vanadium phosphorus oxides (VPO) are very promising materials for the mild oxidation of light alkanes. This is obvious from the considerable knowledge of the physicochemistry of the VPO catalytic system for which many complementary techniques have been used. The present state of the art and the possibilities for the development, in the future, of such a family of catalysts are discussed. It is highly possible that the discovery of new industrial processes for the oxidation of alkanes will stem from the improvement of vanadium phosphorus oxide catalysts. L’état actuel de l'art et les possibilités de développement, dans le futur, des phosphates de vanadium (VPO) sont discutés. La découverte de nouveaux procédés industriels d'oxydation ménagée des alcanes viendra, vraisemblablement, dans l'avenir, d'une modification de la physicochimie des catalyseurs phosphates de vanadium (VPO) afin de les adapter aux nouvelles conditions imposées par le génie de la réaction (procédés à recirculation fonctionnant alternativement en conditions oxydantes et réductrices-réacteurs membranaires).

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