Abstract
New vanadium oxodiperoxocomplexes Bu 4N +[VO(O2) 2 L 2] − were synthesized, where L=pyridine ( 1), 2-methylpyridine ( 2), 4-methylpyridine ( 3), 2-oxymethylpyridine ( 4). All complexes were characterized by NMR ( 1 H , 51 V ) and IR spectroscopy. The oxidation of sulfur organic compounds and diesel fuel desulfurization catalyzed by vanadium peroxocomplexes in bi-phase system was investigated in various solvents. The complexes manifested high catalytic activity and selectivity in oxidation of sulfides.
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