Abstract
Single crystals of vanadium oxychloride have been prepared by reaction between VCl 3 and V 2O 3. An antiferromagnetic behaviour is observed (T N = 150 ± 5 K). Optical and electrical measurements have shown VOCl to be a semi-conductor (∼ 2 eV). The resistivity at room temperature is 5.10 7Ωcm. Lithium can be intercalated electrochemically or through the butyllithium technique. A definite compound Li 0.80VOCl was characterized. Pyridine leads to similar intercalates as in FeOCl.
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