Vanadium-Doped Ni3S2: Morphological Evolution for Enhanced Industrial-Scale Water and Urea Electrolysis.

Abstract

We report the V-Ni3S2 self-supported catalytic network with optimized morphology grown directly on nickel foam (NF) by the one-step hydrothermal technique for water and urea electrolysis at industrial scale hydrogen generation. The morphology of Ni3S2 was modulated by doping of different concentrations of vanadium from granules to cross-linked wires to hierarchal nanosheets arrays, which is beneficial in electrochemical charge and mass transport, and generates more exposed active sites. The V-Ni3S2 catalyst requires the overpotential of 147 mV for hydrogen evolution reaction (HER). The OER and UOR half-cell reaction on V-Ni3S2 catalyst requires potential 1.57 V and 1.39 V (vs RHE), respectively to generate current 100 mA/cm2. The water electrolysis cell developed by V-Ni3S2 as both anode and cathode generates 100 mA/cm2 at cell voltage of 1.88 V in laboratory condition (1M KOH, 25°C) and 1.61 V at industrial condition (5M KOH, 80°C) and also shows considerable stability for 82hr at current 300 mA/cm2. The urea electrolysis cell with 1M KOH and 0.33 M urea generates 100 mA/cm2 at a cell voltage of 1.73 V, which is 150 mV less than that required for water electrolysis and demonstrate stability for 85hr at a current of 100 mA/cm2.